Long?life high?capacity lithium battery with liquid organic cathode and sulfide solid electrolyte

نویسندگان

چکیده

Electrochemical batteries with organic electrode materials have attracted worldwide attention due to their high safety, low cost, renewability, contamination, and easiness of recycling. However, the practical application such system is limited by density, electronic/ionic conductivity, dissolution in conventional liquid electrolytes. Herein, a novel battery configuration proposed replace electrolyte/solid cathode solid electrolyte/liquid ultimately solve shuttle effect problem cathodes. More importantly, this combines room-temperature high-safety lithium metal anode Li-BP-DME that can essentially inhibit dendrite nucleation/growth sulfide SE ultrahigh ionic conductivity for facilitated ion-conduction.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Rechargeable quasi-solid state lithium battery with organic crystalline cathode

Utilization of metal-free low-cost high-capacity organic cathodes for lithium batteries has been a long-standing goal, but critical cyclability problems owing to dissolution of active materials into the electrolyte have been an inevitable obstacle. For practical utilisation of numerous cathode-active compounds proposed over the past decades, a novel battery construction strategy is required. We...

متن کامل

Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery

All-solid-state secondary batteries that employ inorganic solid electrolytes are desirable because they are potentially safer than conventional batteries. The ionic conductivities of solid electrolytes are currently attracting great attention. In addition to the conductivity, the mechanical properties of solid electrolytes are important for improving the energy density and cycle performance. Ho...

متن کامل

Polystyrene-Al2O3 composite solid polymer electrolyte for lithium secondary battery

In a common salt-in-polymer electrolyte, a polymer which has polar groups in the molecular chain is necessary because the polar groups dissolve lithium salt and coordinate cations. Based on the above point of view, polystyrene [PS] that has nonpolar groups is not suitable for the polymer matrix. However, in this PS-based composite polymer-in-salt system, the transport of cations is not by segme...

متن کامل

A novel lithium/sulfur battery based on sulfur/graphene nanosheet composite cathode and gel polymer electrolyte

A novel sulfur/graphene nanosheet (S/GNS) composite was prepared via a simple ball milling of sulfur with commercial multi-layer graphene nanosheet, followed by a heat treatment. High-resolution transmission and scanning electronic microscopy observations showed the formation of irregularly interlaced nanosheet-like structure consisting of graphene with uniform sulfur coating on its surface. Th...

متن کامل

A New Sealed Lithium-Peroxide Battery with a Co-Doped Li2O Cathode in a Superconcentrated Lithium Bis(fluorosulfonyl)amide Electrolyte

We propose a new sealed battery operating on a redox reaction between an oxide (O(2-)) and a peroxide (O2(2-)) with its theoretical specific energy of 2570 Wh kg(-1) (897 mAh g(-1), 2.87 V) and demonstrate that a Co-doped Li2O cathode exhibits a reversible capacity over 190 mAh g(-1), a high rate capability, and a good cyclability with a superconcentrated lithium bis(fluorosulfonyl)amide electr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Battery energy

سال: 2023

ISSN: ['2768-1696', '2768-1688']

DOI: https://doi.org/10.1002/bte2.20220059